Nitrogen (N) fertilizer’s ability to be utilized by a production system is reliant upon the surrounding environment. The state of Oklahoma’s diverse climate presents unique challenges for producers aiming to apply fertilizers effectively and mitigate the adverse effects of unfavorable conditions on nitrogen fertilizers. To lessen the effect that unfavorable environments can have on N fertilizers, chemical additions have been introduced to base fertilizers to give the best possible chance at an impact. With that in mind, a study was conducted to investigate the impact of N sources and application timings on winter wheat grain yield and protein, aiming to identify both the agronomic effects of these sources and how variations in their timing may influence the crop. Included below is a figure of where and when the trials were conducted.
In each of the trials, four N sources (Urea, SuperU, UAN, and UAN + Anvol) were analyzed across a range of timings. The sources were categorized on two criteria: application type, distinguishing between dry and liquid sources, and the presence of additives versus non-additives. The two N sources were Urea and UAN. The other products in this study were SuperU and Anvol. SuperU is a N product that has Dicyandiamide (DCD) and N- (n-butyl) thiophosphoric triamide (NBPT) incorporated into a Urea base. Anvol is an additive product which contains NBPT and Duromide and can be incorporated with dry or liquid N sources.
For additional clarification, N- (n-butyl) thiophosphoric triamide is a urease inhibitor which prevents the conversion of urea to ammonia. Duromide is a molecule which is intended to slow the breakdown of NBPT. DCD is a nitrification inhibitor that slows the conversion of ammonium to nitrate.
Urea is a stable molecule which in the presence of moisture is quickly converted to stable ammonium (NH4), however it can be converted to ammonia gas (NH3) by the enzyme urease beforehand. Additionally, when urea is left on the soil surface and not incorporated via tillage or ½ inch of a precipitation event, the NH4 that was created from urea can be converted back to NH3 and gasses off. So, the use of urease inhibitors is implemented to allow more time for incorporation of the urea into the soil.
Ammonium in the soil is quickly converted to nitrate (NO3) by soil microbes when soil temperature is above 50F°. When N is in the NO3 form it is more susceptible to loss through leaching or denitrification. Therefore, nitrification inhibitors are applied to prevent the conversion of NH4 to NO3.
All treatments were applied at the same rate of 60 lbs of N ac-1, which is well below yield goal rate. A lower N rate was chosen to allow the efficacy of the products to express themselves more clearly, rather than a higher rate that may limit the ability to determine differences between product and rate applied. Furthermore, dry N sources were broadcasted by hand across the plots while liquid sources were applied by backpacking utilizing a handheld boom with streamer nozzles. Application timing dates were analyzed by identifying the growing degree days (GDD) associated with each timing which were correlated with the Feekes physiological growth chart displayed in Figure 3. Over the span of the study, N has been applied over six stages of growth. The range of application dates stems from the fact that it is difficult to get across all the ground exactly when you need to.
Over four years this study was replicated 11 times. Of those 11 site years, three did not show a response to N, so they were removed from further analysis. The graph above shows the average yield of each respective source (across all locations and timings). The data shows there is a statistical difference between SuperU and Urea vs. UAN, but no statistical difference between UAN treated Anvol and any other source. The data indicates that on average, a dry source resulted in a higher yield than when a liquid source was applied. This makes sense considering that in many cases, wheat was planted in heavy residue during cropping seasons that experienced prolonged drought conditions. Therefore, it is thought that a liquid source can get tied up in the residue. This was first reported in a previous blog posting, Its dry and nitrogen cost a lot, what now?, and years later, the same trends in new data indicate the same conclusion.
If we look at all timings and site years averaging together there is no statistical difference between a raw N source and its treated counterpart. This result is not surprising as we would expect that not all environments were conducive to loss pathways that the products prevented. Basically, we would not expect a return on investment in every single site year, and therefore you do not see broad sweeping recommendations. There was a 2-bushel difference between UAN and UAN Anvol. As this was a numerical difference, not a statistical one, I would say that while the yield advantage was not substantial there may be economic environments that would suggest general use.
While the evaluation of the four sources across all timings and locations showed some interesting results, this work was performed to see if there was a timing of application which would have a higher probability of a safened N returning better yields. As you look at the chart above it is good to remember the traditional trend for precipitation in Oklahoma, where we tend to start going dry in November and stay dry through mid-January. Rain fall probability and frequency starts to increase around mid-February, but moisture isn’t consistent until March. This project was performed during some of the dryest winters we have seen in Oklahoma. Also, just a note, since the graph above combines all the sites that have differing application dates the absolute yields are a bit deceiving. For example, the Nov and Feb timings include the locations with our highest yields 80+ bpa per acre, while January and February include our lowest. So, the way this data is represented we should not draw conclusions about best time for N app. For that go read the blogs Impact Nitrogen timing 2021-2022 Version and Is there still time for Nitrogen??
Figure 6a and b. A: The mesonet rainfall totals for Oct -Dec for the Lake Carl Blackwell research station for 2020-2023 A: The mesonet rainfall totals for Jan – April for the Lake Carl Blackwell research station for 2021-2024. The black line on both graphs is the 10 year average.
Now about the source by time. While it’s not always statistical you can see that the dry sources tend to outperform the liquid sources at most timings. Also, while there is never a statistical difference in the raw product and safened, there are trends. SuperU tended to have higher yields than urea when applied in Nov and Dec. It could be hypothesized that the addition of a nitrification inhibitor may have added value, however the UAN + Anvol in November also showed a positive response that would point to the value being derived from urease inhibition. As we move into the period of more consistent rainfall the differences between products start declining, which also makes sense.
The following figures illustrate rainfall events following N application, with the application dates indicated by arrows. Figure 7 corresponds to our trial conducted in 2020-2021, which revealed no statistical differences among the N sources for any timing. However you can see that for the first timing (orange bars) which received 0.7″ of rain two days after application that the yields are uniform than the grey bars with both safened products are numerically greater than the raw product, just makes since as a 0.1″ precipitation event happened 6 days application application and it wasn’t until day 9 that a good incorporating rainfall occurred.
Figure 8 has data the same location one year later, during which we observed statistically significant differences among the dry and liquid N sources. The environmental conditions during 2022 were drier, impacting the incorporation of N applications. The lack incorporating rainfall likely led to tie-up of the UAN on/in the residue, limiting access to plant available N.
It is essential to highlight the environmental conditions encountered throughout this project. From 2020 to 2023, moderate to extreme drought conditions were prevalent. During this period, the influence of a La Niña led to reduced moisture availability. For the first time in an extended period, the 2023-2024 wheat year began under a strong El Niño, which typically results in increased moisture accumulation compared to its La Niña counterpart. Currently, there are indications that a return to a La Niña system may occur by the end of the year, raising the expectation of a potential reversion to drought conditions. Consequently, this research may provide producers with options to consider regarding sources of N application in their production systems.
We plan to update this blog with a deeper analysis of the results seen at each location as soon as possible. But for now, we wanted to share the early look.
At this point the reason for the liquid yield gap is speculation. It could be increased loss via ammonia volatilization or it could be immobilization of the N by microbes. The next step of this process is to understand 1) is the UAN tied up in the residue via immobilization via microbes or is it lost to volatilization. 2) If tied up, what is the time frame between application and immobilization.
Take Home:
- It was observed that during low moisture conditions, dry N sources had significantly better results than liquid counterparts in no-till winter wheat production.
- On average, additive products had no significant impact on grain yield versus base fertilizers, however, when evaluated by location, differences could be found. Responses usually correlated with post-application weather conditions.
- When adequate precipitation was received shortly after application, N sources did not show differences.
Any questions or comments feel free to contact me. b.arnall@okstate.edu
Article courtesy of: Jolee Derrick, Precision Nutrient Management Masters Student.
Brian Arnall, Precision Nutrient Management Specialist. from the Down and Dirty With NKP Blog
